Can one person maintain more than one demat account?

If I want to maintain two different demat account with different brokers, is that possible? Or is it require one demat account for one PAN number?

Yes, I think you can have two different demat accounts.

But one trading account will have one demat account mapped.

Yes with another broker you can have another trading and demat account.

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Yes, most certainly. And more than one Demat Account can be added for one PAN Card.

Also read this for better clarity.
http://tradingqna.com/4156/possible-link-more-than-demat-accounts-same-trading-account

Thanks for answering!