After hour order are orders place when the market is close.You can place orders any time from 6:30 PM to 9:15 AM (until just before market opening).
Check this link for further details -
http://zerodha.com/z-connect/queries/stock-and-fo-queries/pre-marketpost-marketafter-market-orders
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Which trading A/c u r operating?
I have account with several brokers but the above mentioned timings are for Zerodha.
I am Sales Executive in Sharekhan. If you or any of ur friend wants to open Trading A/c Plz inform me.